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Q.

Which of the following statements about anhydrous Aluminium chloride is correct ?

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a

It fumes in moist air.

b

It exists as dimer both in the vapor state below 350°C and in non-polar solvents

c

It is prepared by heating Al2O3 in a stream of sulphur chloride (S2Cl2) vapor and chlorine.

d

All of these.

answer is D.

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Detailed Solution

AlCl3 forms fumes in moist air because of hydrolysis. Hydration energy of Al3+ is very high, therefore AlCl3 can undergo hydrolysis.

AlCl3 is electron-deficient, therefore exist as dimer (Al2Cl6) in both vapor phase and in non polar solvents such as benzene, aniline, and so on.

Formation of AlCl3 from S2Cl2 is:

4Al2O3+3S2Cl2+9Cl28AlCl3+6SO2

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