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Q.

Which of the following statements about critical constants of gases are correct?

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a

Larger  the value of TcPc of  a gas, larger would be the excluded volume

b

Critical temperature (Tc)  of gas is greater than its Boyle’s temperature (Tb)  .

c

At the critical point in the van der Waal’s gas isotherm (PVm)Tc=0  .

d

Vc=3a

answer is A, C.

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Detailed Solution

Larger  TcPc  the value of a gas, larger would be the excluded volume, at the critical point in the van der Waal’s gas isotherm (PVm)Tc=0 

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Which of the following statements about critical constants of gases are correct?