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Q.

Which of the following statements are correct?

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a

Time required for 75% completion is 1.5 times of half-life for zero order reaction

b

Time needed for a definite fraction of 1st order reaction does not vary with the initial concentration

c

Time for 25% reaction is one-third of half life in second order process

d

Rate of 1st order reaction gets doubled if the conc. of the reactant is increased to a twofold value

answer is A.

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Detailed Solution

For zero order (K)=xt

Half lifet12=t1275%

0t1250%t1275%

(1) Time required for75% completion is 1.5 times if half fir zero order reaction.

(2) Time needed for a definite of 1st  order reaction does not very with the initial concentration

(3) Time for 25% reaction is one-third of half-life in second order reaction process.

t=1Kxa(a-x)

x=25a100

=1K25a100aa-25a100

=1K25a100a100a-25a100

=1Ka25a100x10075a

13Ka

t=13t12

4r=KA1

r1=K2A1

r1=Kx2A1

r1=2r

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