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Q.

Which of the following statements are correct?

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a

Anhydrous MgCl2 cannot be prepared by heating MgCl2 · 6H2

b

Anhydrous CaCI2 is used in drying gases and organic compounds but not NH3 or ethyl alcohol due to the formation of CaCl2 · 8NH3 and CaCl2 · 4C2H5OH

c

Leblanc's process is used for preparation of both Na2CO3 and K2CO3 but not solvay process

d

KOH is preferably used compared to NaOH for absorption of CO2 because KHCO3 formed is soluble whereas NaHCO3 is sparingly soluble and therefore, choke the tubes of apparatus used

answer is A.

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Detailed Solution

Anhydrous MgCl2 cannot be prepared by heating MgCl2 · 6H2 as it undergoes partial hydrolysis.

Also, anhydrous CaCI2 is used in drying gases and organic compounds but not NH3 or ethyl alcohol due to the formation of CaCl2 · 8NH3 and CaCl2 · 4C2H5OH

Leblanc's process is used for preparation of both Na2CO3 and K2CO3 but not solvay process

KOH is preferably used compared to NaOH for absorption of CO2 because KHCO3 formed is soluble whereas NaHCO3 is sparingly soluble and therefore, choke the tubes of apparatus used.

Thus, all the options are correct.

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