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Q.

Which of the following statements are correct?

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a

When AgCl react with ClF3 chlorine gas is liberated along with the formation of AgF2

b

Addition of excess chlorine water to KI solution, first gives brown solution which becomes colourless

c

PH4I  is the most stable of PH4X halides with respect to decomposition to PH3 and HX 

d

ClO2  is the major bleaching agent in the pulp industry. 

answer is A, B, C, D.

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Detailed Solution

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A) ClF3 is a strong oxidizing agent and also good fluorinating agent. So it fluorinates the Ag+ ion and oxidize Cl ions when treated with AgCl
 Question Image
B) Chlorine water oxidized KI2 brown I2 solution and then oxidizes to colourless  HIO3
C) PH3 is a weak base, so the stability of its salt increases with increase in the acidic character of HX. Further the H–X bond strength decreases from HF to HX
D) ClO2 is prepared from NaClO3. So use of ClO2 increase the cost.

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