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Q.

Which of the following statements are correct?

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a

Chromyl Chloride is acidic in nature 

b

Chromyl Chloride test must not be performed in the presence of Chlorates 

c

Hydrochloric acid does not give Chromyl chloride test 

d

Chromyl Chloride test should be carried only in dry test tube 

answer is A, B, C, D.

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Detailed Solution

(C,D)-Chromyl Chloride hydrolyses in water forming  CrO3. So,  CrO2Cl2 vapours are not liberated when test is carried in wet test tube or with hydrochloric acid.
A-Chromyl Chloride test must not be carried out in the presence of chrorates because of the danger of forming explosive chlorine dioxide. 
B- chromyl chloride reacts with NaOH

CrO2Cl2+4NaOHNa2CrO4+2NaCl+2H2O

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