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Q.

Which of the following statements are correct?

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a

Ionic product of heavy water  (D2O) is more than ordinary water  (H2O)

b

If the  pD  of  D2O is 7.2, it is acidic in nature.

c

Since O – D bond is stronger than O – H bond ionization of  D2O  is less than  H2O

d

In neutral condition the  pH  and pD of  H2O and  D2O are equal.

answer is B, C.

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Detailed Solution

Ionic product of  D2O(1.35×1015)  is less than ordinary water 1×1014 
D – O bond is stronger than O – H bond so ionization of  D2O is less than  H2O
The  pD value of neutral  D2O is 7.43 so if  D2O  has pD7.2  which is less than  7.43,D2O is acidic. For neutral  H2OpH=7 but for  D2O  is 7.43

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