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Q.

Which of the following statements are correct about half-period?

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a

It is proportional to initial concentration for zeroth order

b

99.9% reaction takes place in 10 minutes for the case when rate constant is 0.693min1

c

Time of 75% completion of reaction is thrice of half-life (initial half-life) period in second order reaction

d

Average life = 1.44 x half-life for first order reaction

answer is A, B, C, D.

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Detailed Solution

The correct statements  about half life-period is

1[A]t=1[A]0+kt4a=1a+k×tt3/4=31ka=3×t1/2

It is proportional to initial concentration for zeroth order

Average life = 1.44 x half-life for first order reaction

Time of 75% completion of reaction is thrice of half-life (initial half-life) period in second order reaction

99.9% reaction takes place in 10 minutes for the case when rate constant is 0.693min1

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