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Which of the following statements are correct about vanderwaals constants(a,b)

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'a' indicates the magnitude of intermolecular attraction

'b' indicates the volume occupied by molecule per mole

'a' depends on temperature and pressure but not on nature of gas

The values of 'a' and ‘b’ depends on nature of gas but not on ‘T’ and ‘p’

answer is A, B, D.

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Detailed Solution

$P^{1} α$ force of attraction impact per see α density $α (conc)^{2} ie P^{1} \times {(\frac{n}{v})}^{2} or P^{1} = a \frac{n^{2}}{v^{2}}$

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