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Q.

Which of the following statements are correct at 25 °C?

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a

pKa for  H3O+ is 15.74

b

pKb  for OH  is 1.74

c

pKa+pKb=pKw for  HCl and ClOH 

d

Degree of dissociation of water is 1.8×107%

answer is B, D.

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Detailed Solution

Ka or  Kb of H2O=1014100018

pKa of H2O=15.74pKbOH=1.74

or pKb of H2O=15.74pKaH3O+=1.74

cα=107 for water

 α=107100018=18×1010 or  1.8×107%

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