Which of the following statements are correct for the first order reaction?

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Half life is independent of initial concentration

Half life is dependent upon temperature

Rate constant of the reaction is dependent upon the temperature

For reaction A $\to$ B the degree of dissociation increases with time and becomes maximum at infinite time

answer is A, B, D.

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Detailed Solution

$t_{1 / 2} \propto \frac{1}{a^{n - 1}}; n = 1; t_{1 / 2} \propto \frac{1}{a^{o}}; t_{1 / 2} = \frac{0.693}{K}$
k = rate constant;
K depends on temperature.
$∴$ t_1/2 also depends on temperature

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