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Q.

Which of the following statements are correct?
I. The hybridisation found in cation PCl4+ is sp3.
II. In AB2L2 type, the BAB bond angle is always greater than the normal tetrahedral bond angle. (L=Lone pairs)
III. In ClO3, NH3 and XeO3, the hybridisation and the number of lone pairs on the central atoms are same.
IV. In discrete P4 molecule, there are six P-P bonds and four lone pairs of electrons.

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a

III and IV only

b

I, II & IV only

c

I, III and IV only

d

I, II and III only

answer is B.

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Detailed Solution

(I) PCl4+sp3
(II) Question Image  has 104.5° bond angle due to lp-lp repulsion.
(III) All have sp3 hybridisation and one lone pair.
(IV) Question Image

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