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Q.

Which of the following statements are correct ?

i)  CH2=CHCH=CH2Br2  40ºC    ii)  CH2=CHCH=CH2Br240ºC

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a

In A the major product is 3, 4-dibromo but -1ene and minor product is 1, 4 dibromobut-2-ene      

b

In A the major product is 1, 4-dibromobut -2ene and 3,4-dibromobut-1ene

c

In B the major product is 1, 4 –dibromobut-2ene and minor product is 3,4 –dibromobut-1ene

d

In B the product is only 3, 4-dibromobut-2-ene

answer is A, C.

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Detailed Solution

At low temperature kinetic product is major and at higher temperature thermodynamic product is major

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