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Q.

Which  of the following Statements  are correct?

a) Micelle formation by soap in aqueous solution is possible at all temperatures.

b) Micelle formation by soap in aqueous solution occurs above a particular concentration.

c) On dilution of soap solution, micelles may revert to individual ions.

d) Soap solution behaves as a normal strong electrolyte at all concentrations. 

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a

a and b

b

b, c and  d

c

b and c

d

a, b and d

answer is C.

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Detailed Solution

Micelle formation: some substances at low concentration behave as a normal electrolytes but higher concentration exhibit colloidal behavior due to the formation of micelles. CMC (Critical Micelle Concentration): the concentration above which Micelle formation takes place as a micelle known as critical micelle concentration (CMC)Eg.., soap solution in aqueous above particular concentration (called CMC=104103 mol  L-1) forms soap micelles.On dilution soap solution behaves as a normal electrolyte and after adding excess of water intermolecular force of attraction between the soap particles decreases and soap solution micelles may revert to individual ions.

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