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Q.

Which of the following statements are correct?

(P) Question Image structure is not allowed because octet around O cannot be expanded.

(Q) H2O2 is an ionic compound.
(R) In B2molecule, the highest occupied molecular orbital is σ molecular orbital.
(S) The lp-bp repulsion, is stronger than bp-bp repulsion.
 

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a

P and S

b

P and R

c

Q and R

d

R and S

answer is C.

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Detailed Solution

The lp-bp repulsion, is stronger than bp-bp repulsion statement is correct.
Because it is not shared by two nuclei, a lp takes up more room than a bp, and the repulsion between the two is stronger between the lp and bp than between the bp and bp. Bond angle distortion because to the presence of lp results in a deviation from the optimum form.
Hence, option C is correct.

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