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Q.

Which of the following statements are INCORRECT?
A) The oxidation states of chromium in CrO42  and  Cr2O72 are not same
  B) The manganate and permanganate ions are tetrahedral due to the π -bonding involves overlap of p-orbitals of oxygen with d-orbitals of manganese.
C) MnO42  ion exhibits d-d transition and paramagnetism as well
D) SO2  gas does not decolourise acidified  KMnO4 solution 

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a

A and D 

b

C and D

c

B and D 

d

A and B 

answer is A.

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Detailed Solution

The oxidation state of chromium in  CrO42 and  Cr2O72 ions are same i.e, +6
 SO2 gas readily decolurises acidified KMnO4  solution. 
2MnO4+5SO2+2H2O2Mn+2+5SO42+4H+Pinkcolour                             Colourless

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