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Q.

Which of the following statements are not correct.
A) For isothermal process ΔU=0
B) The heat content of the products is more than that of the reactants in an exothermic reaction
C) The heat of neutralisation between HCl and NaOH always equal to --57.3 KJ / mole
D) A system is said to be closed system if it can neither exchange matter nor energy with the surroundings

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a

B & D only

b

A & B only

c

A & C only

d

A,B,C

answer is B.

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Detailed Solution

(A) ΔU=nCvΔT

For isothermal ΔT=0ΔU=0

(B) HP>HR  “H= +Ve,   endothermic

(C) H3BO3+H2O[B(OH)4]+H3O

(D) In Isolated system both matter and energy not exchanged with surroundings

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