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Q.

Which of the following statements are true about P4O6 and P4O10?

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a

Both these oxides have a closed cage like structure

b

Each oxide requires 6 water molecules for complete hydrolysis to form their respective oxoacids.

c

Both these oxides contain 12 equivalent P–O bonds

d

P4O6 and P4O10 both contains  bonds

answer is A, B, C, D.

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Detailed Solution

Question Image

(a) 12 equivalent P–O bonds (160pm) 12 equivalent P – O bonds (160pm) 4 P – O dative bonds (140pm)
(b) P4O6+6H2O4H3PO3 ortho phosphorous acid
P4O10+6H2O4H3PO4 ortho phosphoric acid

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