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Q.

Which of the following statements is / are correct ?
I) 5 moles of CO2 and 5 moles of H2 O have the same mass.
II) 100 g of NH3 has more atoms than that present in 100 g of N2
III) 16 g of solid sulphur contains 3.76x1022 molecules

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a

I and II only

b

III only

c

II and III only

d

I only

answer is B.

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Detailed Solution

5 moles of CO2 - 220g
5 moles of H2O -90g
So they have different mass
17g of NH3 - 4NA atoms
100g of NH3 - 4 x 5.88NA atoms
 28g of N2 - 2NA atoms
100g of N2 - 2x7.1NA atoms
So 100 g of NH3 has more atoms
In solid form sulphur exist as S8
6.023 x 1023 molecules – 1 mole of solid sulphur
8x32g of sulphur - 6.023 x 1023
16 g of sulphur – x
x=6.023×1023×168×32=3.76×1022

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