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Q.

Which of the following statements is/are correct?

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a

The co-ordination number of each type of ion in CsCl crystal is 8 

b

A metal that crystallizes in b.c.c. structure has a co-ordination number of 12

c

A unit cell of an ionic crystal shares some of its ions with other unit cells

d

The length of the unit cell in NaCl is 552 pm rNa+=95pm,rCl=181pm

answer is A.

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Detailed Solution

  • Cs+ ion is surrounded by 8 Cl- ions at the corners of unit cell. Also, Cl- ion is also surrounded by 8 Cs+ ions. Therefore, coordination number of Cs in CsCl is 8 . 
  • The unit cell of an ionic crystal shares some of its ions with other unit cells like corner ions, face center ions.
  • The length of the unit cell in NaCl is 552 pm rNa+=95pm,rCl=181pm
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