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Q.

Which of the following statements is/are correct?

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a

The stability constant of CoNH363+is greater than that of CoNH362+

b

Among F-, Cl-, Br- and I-, F- forms more stable complexes due to small size.

c

CuNH342+ is thermodynamically more stable than ZnNH342+

d

Among Fe(CN)63FeH2O62+ and  Fe(en)33+,Fe(CN)63-  is most stable.

answer is A.

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Detailed Solution

(a) The stability constant of CoNH363+is greater than that of CoNH362+because of the crystal field splitting Effect.

(b) Among F-, Cl-, Br- and I-, F- forms more stable complexes due to small size because F is S.F.L.

(c) According to Irving Williama order, stability of +2 oxidation state for 3d transition series follows :

MnII<FeII<CoII<NiII<CuII>ZnII

Hence, the correct option is a, b and c.

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