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Q.

Which of the following statement(s) is/are correct?

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a

The oxidation state of iron in sodium nitro prusside Na2[Fe(CN)5(NO)]  is +II

b

[Ag(NH3)2]+ is linear in shape

c

In [Fe(H2O)6]3+, Fe is d2sp3  hybridized

d

In [Co(H2O)6]3+  complex ion, Co is d2sp3 hybridized

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Detailed Solution

Oxidation state of Fe in Na2[Fe(CN)5(NO)] is:

2(+1)+oxidation state of Fe+5(-1)+1=0 oxidation state of Fe=+2

Complex, [Ag(NH3)2]+ has sp hybridization and has a linear shape.

Complex, [Co(H2O)6]3+has +3 oxidation state on the central atom. [Co(H2O)6]3+ has d2sp3 hybridization.

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