Q.

Which of the following statements is/are correct about solubility
Where k is equilibrium constant for the reaction ZnS(s)+2Haq+Znaq+2+H2Saq

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a

Solubility of ZnS in water depends on pH of solution

b

Solubility of ZnS in the presence of H+ ion can be derived by k=zn+2H2SH+2

c

Solubility of CaF2 is more in buffer solution of pH = 3 than in pure water

d

Solubility of AgCl increase in presence of sodium thiosulphate

answer is A, B, C, D.

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Detailed Solution

A) In acid solution F- is removed 
B) S-2 reacts with H+ 
C) Ag+ is removed as a complex
D) ZnsZn+2+s2 KspH2S2H++S2Ka;KspKa=k

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