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Q.

Which of the following statements is/are true?

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a

Ag+ ions do not give white precipitate with concentrated HCl.

b

Cu2+ ions produce a white precipitate when KCN solution is added in a small quantity 

c

Hg2+ ions give deep blue precipitate with cobalt acetate and ammonium thiocyanate

d

Black precipitate of BiI3 turns orange when heated with water.

answer is A.

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Detailed Solution

Ag+ ions do not give white precipitate with concentrated HCl

.AgCl2(soluble) 

Cu2+ ions produce a white precipitate when KCN solution is added in a small quantity 

Cu(CN)2↓⟶CuCN(White)+(CN)2

Hg2+ ions give deep blue precipitate with cobalt acetate and ammonium thiocyanate

Hg2++Co2++4SCNCoHg(SCN)4(Deep blue)

Black precipitate of BiI3 turns orange when heated with water.

BiOI (Orange)

All options are correct.

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