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Q.

Which of the following statements is/are true 

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a

for substance  ΔSvap0>ΔSfusion0 in general

b

greater amount of heat will be required to dissociate NH3  gas into N2  and  H2 at constant pressure condition as compared to constant volume condition at same temperature.

c

The reaction having rate law, r=k[A]2[B]  will follow first order kinetics if [A] is very high and third order kinetics if [B] is very high.

d

Graphite being standard allotrope of carbon, graphite has less standard entropy (Sm0)  than diamond.

answer is A, B.

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Detailed Solution

ΔG  doesn’t explain rate law of reaction at  PH12  ΔG0=96500E10
at  PH<12  ΔG0=96500×3E20

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