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Q.

Which of the following statements is/are wrong?

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a

Benzene diazonium chloride gives positive Lassaigne’s test

b

Aniline cannot give positive Lassaigne’s test 

c

When FeCl3 solution is added to the Lassaigne’s extract, a blue solution is obtained, which indicates the presence of both nitrogen & sulphur.

d

In Lassaigne’s test for nitrogen, Prussian blue colour due to the formation of ferroferri cyanide

answer is A, B, C, D.

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Detailed Solution

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Benzene diazonium chloride does not  give positive lassaigne’s test because they loose N2 gas even at moderate temperatures.

In lassaigne’s test for nitrogen, Prussian blue colour due to the formation of the ferric  –ferro cyanide

When FeCl3 solution is added to the Lassaigne’s extract, a blue solution is obtained, which indicates the presence of nitrogen

Aniline can give positive Lassaigne’s test 

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