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Q.

Which of the following statement(s) is are/correct

 

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a

A plot of logK vs  1Tis linear (T is temperature)

b

A plot of ‘r’ vs ‘C’ is a straight line passing through the origin for the first order reaction

c

A plot of log p vs1/Tis linear at constant V (P is pressure, T is temperature)

d

C’ vs ‘t’ is a straight line for zero order reactions

answer is A, B, C, D.

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Detailed Solution

(1) K=A.e-Ea/RT 

logK=logA+loge eEa/RT

logK=logA-Ea2.303RT

logK=logA+-EaR1T

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(2) r[C]1

r[c]1

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(3) logPKT

The calusius clapeyron equation states that 𝑃 = 𝐴e −Δ𝐻 / 𝑅𝑇

Taking log both sides, we have log𝑃  = log𝐴 − HRT

Graph of log𝑃 𝑉𝑠  1Tis thus a straight line with slope -HRand intercept log A

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(4) r[c]°

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