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Q.

Which of the following statements is correct?

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a

Alkaline hydrolysis of an ester is a reversible reaction.

b

In the alkaline hydrolysis of an ester, the bond broken is the bond between oxygen and alkyl group.

c

Alkaline hydrolysis of an ester follows second order kinetics and is thus SN2.

d

An electron-withdrawing group G in pGC6H4COOC2H5 decreases the rate of hydrolysis as compared to C6H5COOC2H5.

answer is C.

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Detailed Solution

(a) The reaction is

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The reaction is irreversible because the resonance-stabilised carboxylate anion shows little tendency to react with an alcohol.

(b) The bond broken is the bond between oxygen and acyl carbon.

(d) An electron-withdrawing group stabilises the intermediate carboxylate anion, hence speeds up the rate of hydrolysis.

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Which of the following statements is correct?