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Q.

Which of the following statements is correct?

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a

Tautomers differ in the arrangement of atoms and are also in rapid equilibrium with each other

b

Keto-enol tautomerism is an equilibrium between two acids favouring the formation of the stronger acid.

c

A pair of electron in an sp hybrid orbital of carbon is less near to the nucleus as compared to that in an sp3 hybrid orbital.

d

2-Butyne reacts with ammoniacal silver nitrate solution.

answer is A.

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Detailed Solution

(b) Equilibrium reaction always favours the formation of weaker substances. In keto-enol tautomerism, we have

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( c) An sp hybrid orbital has more s-character as compared to an sp3 hybrid orbital.

(d) 2-butyne does not contain acetylinic hydrogen atom.

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