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Q.

Which of the following statements is correct?

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a

The reaction CH33CBr+OHCH33COH+Br proceeds via SN1mechanism.

b

The reaction CH3CH2Br+OHCH3CH2OH+Br proceeds via SN1 mechanism

c

The reaction Question Image

proceeds via SN1 mechanism

 

d

The reaction Question Image

proceeds via SN2 mechanism.

answer is A.

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Detailed Solution

(a) Since 3° carbocation is most stable, the reaction proceeds via the formation of 3° carbocation, i.e. SN1

(b) Since 1 ° carbocation is least stable, the reaction does not proceed via the formation of carbocation, i.e. SN2

( c) Since there is inversion in optical rotation, the reaction must have proceeded via SN2 mechanism.

 ( d) Since there is no inversion in optical rotation, the reaction must have proceeded by SN 1 mechanism as in SN2 there occurs inversion of configuration of carbon atom.

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