Which of the following statements is correct?

The reaction of benzene with n-propyl chloride in the presence of $\mathrm{A}1{\mathrm{Cl}}_3$ gives 1-phenylpropane as the only product

Though -$\mathrm{N}{\left({\mathrm{CH}}_3\right)}_2$ is an ortho- and para-director yet it gives meta nitrated product with the more powerful electrophilic reagent ${\mathrm{HNO}}_3/{\mathrm{H}}_2\mathrm{S}{0}_4$

Phenyl cation is more stable than cyclohexyl cation

Benzene-water forms a higher boiling azeotrope