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Q.

Which of the following statements is correct?

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a

The processes Xe(g)Xe+(g)+e and O2(g)O2+(g)+e involve more or less identical ionization energy

b

XeF2 possesses an angular structure

c

XeF2F possesses a trigonal bipyramidal structure with xenon and fluorine atoms occuping linear position and the three lone pairs occupying equatorial position

d

XeF4 is regarded as pseudo-octahedral with fluorines occupying the corners of a square plane

answer is B.

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Detailed Solution

XeF2 molecule has a trigonal bipyramidal structure. In XeF2, there are three lone pairs and two bond pairs for a total of five electron pairs. Five electron pairs create a trigonal bipyramidal structure. 

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