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Q.

Which of the following statements is correct?

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a

The addition of HBr to 1,3-butadiene produces both l-bromo-2-butene and 3-bromo-1-butene which are in equilibrium with each other. The relative amounts of the two are temperature dependent.

b

The addition of HBr to 1,3-butadiene at 40 °C produces 3-bromo-1-butene as the major product.

c

The treatment of gaseous propene with chlorine at 500-600 °C yields 1,2-dichloropropane.

d

The addition of HBr to 1,3-butadiene at - 80 °C produces l-bromo-2-butene as the major product.

answer is C.

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Detailed Solution

(a) At lower temperature, 1,2-adduct predominates over the 1,4-adduct. Hence, the major component is 3-bromo1-butene. 

(b) At higher temperature, 1,4-adduct predominates over the 1,2-adduct. Hence, the major component is 1-bromo-2-butene. 

( d) At the given conditions, substitution at alkyl group takes place. This gives allyl chloride.

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