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Q.

Which of the following statements is correct ?

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a

alkynes are less reactive than alkenes towards halogen addition

b

primary vinylicRCH=C+H cation  is more reactive than secondary vinylic cation RCH=C+H2

c

alkynes are more reactive than alkenes towards halogen addition

d

both alkynes and alkenes are equally reactive towards halogen addition

answer is B.

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Detailed Solution

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  • Alkynes are less reactive towards electrophilic addition reaction due to formation of vinylic cation which is less stable.
  •  In electrophilic addition reaction carbocation formation takes place as an intermediate on electrophile attack. 
  • so more reactive alkene or alkyne for electrophilic addition reaction.
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