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Which of the following statements is correct?

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1° amide liberates $N_{2}$ when treated with ${HNO}_{2}$

2° amide liberates $N_{2}$ when treated with ${HNO}_{2}$

3° amide liberates $N_{2}$ when treated with ${HNO}_{2}$

None of 1 °, 2° and 3° amides liberate $N_{2}$ when treated with ${HNO}_{2}$

answer is A.

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Detailed Solution

Statement A is correct. 1° amide liberates $N_{2}$ when treated with ${HNO}_{2}$ .

When nitrous acid and primary amine combine, only primary amine produces nitrogen gas. While nitrosamine is produced by secondary amine and ammonium salt is produced by tertiary amine.

Hence, option A is correct.

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