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Q.

Which of the following statements is correct in the context of the allene molecule.C3H4?

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a

The central carbon is sp hybridized

b

The terminal carbon atoms are sp2 hybridized

c

The planes containing the CH2 groups are mutually perpendicular to permit the formation of two separate π-bonds.

d

All correct

answer is D.

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Detailed Solution

The central C atom in the allene molecule is sp hybridized, and the remaining two C atoms are sp2hybridized.
As a result, the central C atom possesses two double bonds, compared to just one double bond for each of the other two C atoms.
There are two unhybridized p orbitals present on the central carbon atom which are mutually perpendicular. These two unhybridized p orbitals are used to form two pi bonds with two adjacent C atoms.
Hence, the planes containing the CH2 groups are mutually perpendicular.
Thus,

The statements A, B and C are correct.

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