Q.

Which of the following statements is correct regarding a solution of two components A and B exhibiting positive deviation from ideal behaviour?

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a

Intermolecular attractive forces between A-A and B-B are equal to those between A-B.

b

mixV=0 at constant T and P.

c

Intermolecular attractive forces between A-A and B-B are stronger than those between A-B.

d

mix H = 0 at constant T and P.

answer is B.

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Detailed Solution

Solution exhibiting positive deviation from ideal behaviour must have weaker A – B interactions than A – A and B – B interactions.

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