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Q.

Which of the following statements is false?

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a

Strontium decomposes water readily than beryllium

b

Barium carbonate melts at a higher temperature than calcium carbonate

c

Barium hydroxide is more soluble in water than magnesium hydroxide

d

Beryllium hydroxide is more basic than barium hydroxide

answer is D.

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Detailed Solution

Be Mg Ca Sr Ba As the size increases, metallic nature increases, reactivity with water increases, therefore “Sr” decomposes water readily than Be.

Option - 1 correct

Melting Points order

BeCO3<MgCO3<CaCO3<SrCO3<BaCO3 As the size  [Molecular weight] of carbonates increases, surface area increases, inter molecular attraction increases and hence melting point increases

Option -2 is correct

solubility order

BeOH2<MgOH2<CaOH2<SrOH2<BaOH2 If anion size is smaller [F- , OH- ] then solubility depends on lattice energy 
As L.E decreases from Be(OH)2 to Ba(OH)2 ,solubility increases.
So option 3 also correct.

Basic strength Order:

BeOH2<MgOH2<CaOH2<SrOH2<BaOH2
As the size of metal increases, metallic nature increases, ionisation of M-OH bond increases, release of OH- ion increases
Basic strength increases

So Option -4 Incorrect

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Which of the following statements is false?