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Which of the following statements is incorrect?

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In ClF₃ , the axial $Cl - F$ bond length is longer than equatoria l $Cl - F$ bond length

In SF₄ , $F - S - F$ equatorial bond angle is not 120° but 104° due to $l p - b p$ repulsions.

ln $[{ICl}_{4}^{-} Cl - I - Cl$ bond angle is 90°

In OBr₂ , the bond angle is less than that in ${OCl}_{2}$ .

answer is D.

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Detailed Solution

In OBr₂ , the bond angle is less than that in ${OCl}_{2}$ .

${OBr}_{2} > {OCl}_{2}$

Since the core atom is identical and their hybridization is also identical, the bond angle between OF₂, H₂O, and OCl₂ will rely on the electronegativity of the surrounding atoms.

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