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Q.

Which of the following statements is incorrect?

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a

 NiBr2PEt32  and CuNH34NO32 have same geometrical but different magnetic properties

b

CoNH33ClCl2 and K4Cr(CN)63H2O both are inner orbital complexes but the former is diamagnetic and later one is paramagnetic with two unpaired electrons.

c

CoNH32Cl2(en)+can have total five stereo isomeric forms.

d

Complex PtNH34PtCl6 can show coordination isomerism

answer is C.

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Detailed Solution

NiBr2PEt32 and CuNH34NO32 have the same geometry and magnetic properties since there are the same number of unpaired electrons.

CoNH32Cl2(en)+can have total five stereo isomeric forms.

Due to structural isomer -1's plane of symmetry (ionization/isomer), there are no optical isomers.

CoCl3NH33NH3 Geometrical - 2 (lix se frans)

Total number of isomer is:2+1= 3

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