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Q.

Which of the following statements is incorrect

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a

In equilibrium mixture of ice and water kept in perfectly insulated flask mass of ice and water does not change with time.

b

The intensity of red colour increases when oxalic acid is added to a solution containing iron (III) nitrate and potassium thiocyanate.

c

On addition of catalyst the equilibrium constant value is not affected.

d

Equilibrium constant for a reaction with negative ΔH value decreases as the temperature increases.

answer is B.

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Detailed Solution

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Fe3++SCN[Fe(SCN)]2+  Oxalate complexes with Fe3+ shifts 
Yellow                       Red
equilibrium to left

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