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Q.

Which of the following statements is incorrect?

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a

In both  [Ni(CO)4]  and  [Ni(CN)4]2 , the central  metal atom/ion is in the same hybridised state

b

There are 5 atoms lying in same plane in anionic part of ‘Z’ 
 CuSO4+KCN(excess)Z(contains   Cu)+side  products

c

B2  molecule will be diamagnetic when 2s – 2p mixing is operative and Hund’s rule  is violated

d

Both ZnO and V2O5  are amphoteric in nature

answer is A.

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Detailed Solution

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Hint:   [Ni(CO)4] :   Ni0:  sp3
[Ni(CN)4]2  :   Ni2+ :  dsp2

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