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Which of the following statements is not correct?

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The molecule of ${NO}_{2}$ is angular

Low temperatures favours the dimerization of ${NO}_{2}$ to $N_{2} O_{4}$

${NO}_{2}$ is soluble in water giving a mixture of ${HNO}_{2}$ and ${HNO}_{3}$

The structure of $N_{2} O_{4}$ is nonplanar

answer is D.

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Detailed Solution

The structure of $N_{2} O_{4}$ is planar. The coplanarity of $N_{2} O_{4}$ results from a delicate balance of the repulsive forces, which favor the skew structure, and of the effects of bonding which favor the planar structure.

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