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Q.

Which of the following statements is not correct?

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a

The stability of the +4 oxidation state of elements of Group 14 decreases down the group

b

The stability of the +2 oxidation state of elements of Group 14 increases down the group

c

Stannous fluoride is a covalent compound

d

A majority of the compounds of elements of Group 14 are four covalent and involve sp3 hybridization

answer is A.

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Detailed Solution

The stability of the +4 state decreases on moving down the group while that of the +2 state increases. This is due to the inert pair effect. The elements of this group can show a +4 oxidation state only when their ns² electron pair gets excited to np orbitals.

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