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Q.

Which of the following statements is not correct?

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a

Quaternary ammonium salts in which nitrogen holds four different groups show optical activity

b

Aliphatic amines can be prepared by ammonolysis of alkyl halides but not aromatic amines.

c

Ammonolysis of alkyl halides gives highest yield with tertiary halides and is worthless for primary halides.

d

The more stable the substituted ammonium ion relative to the amine from where it is formed, the more basic is the amine 

answer is C.

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Detailed Solution

(a) Aryl halides have low reactivity toward nucleophilic substitution

( b) Ammonolysis gives good yield with primary amines as nucleophilic substitution predominates but is worthless for tertiary amines as elimination reaction predominates to give alkenes.

CH3CH2CH2BrNH3CH3CH2CH2NH3+Br ; Question Image

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