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Which of the following statements is not correct?

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${({CH}_{3})}_{3} COH$ is less acidic than ${({CH}_{3})}_{3} SiOH .$

Like ${CO}_{2}$ its analogue of Si is not stable.

In phosgene, C-O bond length is longer than expected while C-Cl bond length is shorter.

None pof the above.

answer is D.

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Detailed Solution

$O = Si = O$ does exist because $3 p π - 2 p π$ is highly unstable.

(Due to resonance, $C - Cl$ boiling point $↓$ and $C - O$ boiling point increases).

Here, all the statements are correct.

Hence, option D is correct.

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