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Q.

Which of the following statements is not correct?

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a

An organic compound on treating with HIO4 gives CH3COCH3 and HCHO. The compound is

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b

An organic compound on treating with HIO4 gives 5HCOOH and one HCHO. The compound is

Question Image

 

c

Thiols are less soluble in water as compared to the corresponding alcohols.

d

Thiol CH3SH is more acidic than CH3OH.

answer is B.

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Detailed Solution

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(b) The compound is Question Image

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(c) Thiols are less polar than the alcohols.

(d) The negative charge on S (which is larger in size than oxygen) is more spread on its conjugate base RS of the acid RSH as compared to that on O of RO  Thus, RS is less likely to attract H+ than RO , making RSH more acidic than ROH.

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