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Q.

Which of the following statements is not correct?

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a

The addition of acetylene to lithium amide dissolved in ether produces NH3 and HCC¯Li+.

b

If water can generate HCCH from HCCLi then water must be a stronger acid than acetylene.

c

Acetylide ion (which has a pair of electrons in sp orbital of carbon) is more stronger base than ethide ion, C2H5 (which has a pair of electrons in sp3 orbital of carbon).

d

Lindlar catalyst is Pb/BaSO4.

answer is C.

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Detailed Solution

( c) Acetylide is a weaker base than ethide ion. A pair of electrons is more tightly bound in acetylene than in ethide ion.

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