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Which of the following statements is not correct?

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In pinacol-pinacolone rearrangement reaction involving,

the phenyl group migrates in preference to methyl group.

In pinacol-pinacolone rearrangement reaction involving

the $3^{\circ} OH$ is lost, followed by :H migration.

Schiff base is N-substituted imine.

In the Beckmann rearrangement reaction

the product A is R'CONHR.

answer is D.

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Detailed Solution

(a) The reaction is

(b) The reaction is

$RCHO + R^{'} {NH}_{2} \overset{- H_{2} O}{\to} RCH = N - R^{'}$

(d) It is the trans R¢ group which migrates

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