Q.

Which of the following statements is not correct?

see full answer

Start JEE / NEET / Foundation preparation at rupees 99/day !!

21% of IItians & 23% of AIIMS delhi doctors are from Sri Chaitanya institute !!
An Intiative by Sri Chaitanya

a

The overall rate of an electrophilic substitution reaction, except sulphonation in benzene and deuterated benzene, are identical

b

The C-H bond in benzene is slightly stronger than the C-D bond in deuterated benzene (C6D6).

c

In electrophilic aromatic substitution reaction, the formation of intermediate arenium cation is the ratedetermining step.

answer is B.

(Unlock A.I Detailed Solution for FREE)

Ready to Test Your Skills?

Check your Performance Today with our Free Mock Test used by Toppers!

Take Free Test

Detailed Solution

(a) The formation of intermediate arenium cation is slow while the elimination of H+ from this cation is fast. The former involves the removal of aromaticity while the latter restores aromaticity

(b) The C-D bonds are stronger than C-H bonds. In fact, the bond with the heavier isotope is slightly stronger than that with the lighter isotope.

( c) In electrophilic substitution reactions, the rate-determining step is the formation of arenium cation. Question Image

In this step, E+ bonds to the aromatic ring without cleavage of a C-H bond. The latter is broken in the second step, which is fast as it restores the stable aromatic system. Since C-H or C-D bond is not broken in the rate-determining step, the overall rates of reaction are identical.

 

Watch 3-min video & get full concept clarity

tricks from toppers of Infinity Learn

score_test_img

Get Expert Academic Guidance – Connect with a Counselor Today!

whats app icon